============================================================================= SHIFTS, version 4.1 [X.-P. Xu and D.A. Case, Mar. 2002] ============================================================================= shifts will be computed for atoms matching ::H* found 5 rings ring int. center anis. iso. HIS 5 0.900 -20.481 2.968 20.345 -99.200 -91.000 HIS 6 0.900 -15.362 0.277 15.659 -99.200 -91.000 PHE 7 1.000 -21.912 1.400 12.940 -99.200 -91.000 PHE 17 1.000 -11.405 3.183 3.520 -99.200 -91.000 TYR 32 0.840 11.742 3.193 13.377 -99.200 -91.000 ============================================================================= Atom RingCur El P_anis Const RC pred Obs ============================================================================= 1afoA5 VAL 62 HA -0.03 -0.04 0.13 -0.75 4.13 3.43 1afoA5 VAL 62 HB -0.02 -0.06 0.13 -0.04 2.12 2.13 1afoA5 VAL 62 HG13 -0.01 -0.00 0.03 -0.04 0.97 0.94 1afoA5 VAL 62 HG23 -0.01 0.01 -0.12 -0.04 0.95 0.79 1afoA5 GLN 63 H -0.02 0.19 0.13 -0.55 8.47 8.22 1afoA5 GLN 63 HA 0.00 0.18 0.70 -0.75 4.36 4.48 1afoA5 GLN 63 HB2 0.02 -0.19 0.04 -0.04 2.15 1.98 1afoA5 GLN 63 HB3 -0.01 0.13 -0.02 -0.04 2.02 2.08 1afoA5 GLN 63 HG2 -0.05 0.04 -0.11 -0.04 2.40 2.24 1afoA5 GLN 63 HG3 -0.05 -0.08 -0.22 -0.04 2.39 2.01 1afoA5 GLN 63 HE21 0.16 0.08 -0.18 -0.04 6.97 6.98 1afoA5 GLN 63 HE22 0.19 -0.01 -0.32 -0.04 7.69 7.51 1afoA5 LEU 64 H 0.02 0.16 0.14 -0.55 8.37 8.15 1afoA5 LEU 64 HA 0.01 0.23 0.86 -0.75 4.35 4.70 1afoA5 LEU 64 HB2 0.03 -0.01 0.05 -0.04 1.64 1.67 1afoA5 LEU 64 HB3 0.04 0.01 0.08 -0.04 1.64 1.73 1afoA5 LEU 64 HG 0.04 0.02 0.10 -0.04 1.64 1.76 1afoA5 LEU 64 HD13 0.02 0.03 -0.17 -0.04 0.93 0.77 1afoA5 LEU 64 HD23 0.03 -0.00 0.02 -0.04 0.89 0.90 1afoA5 ALA 65 H 0.05 -0.00 -0.08 -0.55 8.40 7.82 1afoA5 ALA 65 HA 0.08 0.09 0.56 -0.75 4.34 4.31 1afoA5 ALA 65 HB3 0.09 0.02 0.14 -0.04 1.41 1.61 1afoA5 HIS 66 H 0.16 0.39 0.14 -0.55 8.41 8.55 1afoA5 HIS 66 HA 0.07 -0.06 0.24 -0.75 4.63 4.12 1afoA5 HIS 66 HB2 0.01 0.03 0.16 -0.04 3.26 3.43 1afoA5 HIS 66 HB3 -0.01 -0.00 -0.05 -0.04 3.20 3.09 1afoA5 HIS 66 HD2 0.02 0.04 0.05 -0.04 6.97 7.03 1afoA5 HIS 66 HE1 0.03 -0.01 0.01 -0.04 7.75 7.74 1afoA5 HIS 67 H -0.12 0.00 0.10 -0.55 8.41 7.85 1afoA5 HIS 67 HA -0.56 -0.08 0.43 -0.75 4.63 3.67 1afoA5 HIS 67 HB2 -0.05 0.01 -0.55 -0.04 3.26 2.63 1afoA5 HIS 67 HB3 -0.09 0.01 0.06 -0.04 3.20 3.14 1afoA5 HIS 67 HD2 -0.10 -0.03 0.02 -0.04 6.97 6.82 1afoA5 HIS 67 HE1 -0.04 -0.01 -0.02 -0.04 7.75 7.64 1afoA5 PHE 68 H -1.01 0.15 0.18 -0.55 8.34 7.10 1afoA5 PHE 68 HA 0.00 0.17 0.74 -0.75 4.62 4.78 1afoA5 PHE 68 HB2 -0.03 0.04 -0.02 -0.04 3.15 3.10 1afoA5 PHE 68 HB3 -0.01 0.12 -0.02 -0.04 3.06 3.11 1afoA5 PHE 68 HD2 -0.04 0.12 -0.17 -0.04 7.28 7.14 1afoA5 PHE 68 HE2 -0.06 0.00 -0.05 -0.04 7.38 7.23 1afoA5 PHE 68 HZ -0.03 0.01 -0.01 -0.04 7.32 7.24 1afoA5 SER 69 H 0.12 0.19 0.16 -0.55 8.46 8.38 1afoA5 SER 69 HA 0.05 0.20 0.89 -0.75 4.49 4.87 1afoA5 SER 69 HB2 0.02 0.02 -0.05 -0.04 3.95 3.90 1afoA5 SER 69 HB3 0.00 -0.00 0.05 -0.04 3.93 3.94 1afoA5 GLU 70 H -0.00 0.11 -0.01 -0.55 8.60 8.14 1afoA5 GLU 70 HA -0.00 0.03 0.36 -0.75 4.29 3.92 1afoA5 GLU 70 HB2 -0.00 0.21 0.43 -0.04 2.09 2.68 1afoA5 GLU 70 HB3 -0.00 -0.03 -0.30 -0.04 1.99 1.62 1afoA5 GLU 70 HG2 -0.02 -0.12 -0.14 -0.04 2.34 2.02 1afoA5 GLU 70 HG3 -0.02 0.03 0.02 -0.04 2.34 2.32 1afoA5 PRO 71 HA -0.05 0.10 0.41 -0.51 4.44 4.38 1afoA5 PRO 71 HB2 -0.14 -0.07 0.24 -0.04 2.28 2.26 1afoA5 PRO 71 HB3 -0.08 0.09 0.13 -0.04 2.02 2.11 1afoA5 PRO 71 HG2 -0.08 0.07 0.08 -0.04 2.03 2.06 1afoA5 PRO 71 HG3 -0.04 0.12 0.05 -0.04 2.03 2.11 1afoA5 PRO 71 HD2 -0.01 -0.07 0.10 -0.04 3.68 3.66 1afoA5 PRO 71 HD3 -0.01 0.23 -0.04 -0.04 3.65 3.79 1afoA5 GLU 72 H -0.03 0.60 0.49 -0.55 8.60 9.11 1afoA5 GLU 72 HA -0.03 0.06 0.35 -0.75 4.29 3.91 1afoA5 GLU 72 HB2 -0.02 0.06 0.28 -0.04 2.09 2.36 1afoA5 GLU 72 HB3 -0.02 0.01 0.08 -0.04 1.99 2.03 1afoA5 GLU 72 HG2 -0.01 -0.02 0.05 -0.04 2.34 2.31 1afoA5 GLU 72 HG3 -0.01 0.07 0.09 -0.04 2.34 2.44 1afoA5 ILE 73 H -0.03 0.18 0.05 -0.55 8.25 7.89 1afoA5 ILE 73 HA -0.02 0.05 0.37 -0.75 4.18 3.83 1afoA5 ILE 73 HB -0.02 0.04 0.14 -0.04 1.89 2.01 1afoA5 ILE 73 HG12 -0.01 0.05 -0.04 -0.04 1.49 1.45 1afoA5 ILE 73 HG13 -0.01 -0.04 0.04 -0.04 1.21 1.15 1afoA5 ILE 73 HG23 -0.04 0.00 -0.07 -0.04 0.93 0.78 1afoA5 ILE 73 HD13 -0.00 0.01 0.03 -0.04 0.88 0.88 1afoA5 THR 74 H -0.10 0.01 -0.49 -0.55 8.28 7.16 1afoA5 THR 74 HA -0.22 0.03 0.37 -0.75 4.39 3.82 1afoA5 THR 74 HB -0.34 0.11 0.07 -0.04 4.32 4.12 1afoA5 THR 74 HG23 -0.41 0.01 0.05 -0.04 1.22 0.82 1afoA5 LEU 75 H -0.16 0.62 -0.03 -0.55 8.37 8.25 1afoA5 LEU 75 HA -0.14 0.01 0.49 -0.75 4.35 3.95 1afoA5 LEU 75 HB2 -0.08 0.03 0.13 -0.04 1.64 1.68 1afoA5 LEU 75 HB3 -0.03 0.00 0.11 -0.04 1.64 1.68 1afoA5 LEU 75 HG -0.01 0.00 0.04 -0.04 1.64 1.63 1afoA5 LEU 75 HD13 0.00 -0.00 -0.04 -0.04 0.93 0.85 1afoA5 LEU 75 HD23 0.05 -0.01 -0.07 -0.04 0.89 0.82 1afoA5 ILE 76 H -0.03 0.73 0.02 -0.55 8.25 8.42 1afoA5 ILE 76 HA 0.03 0.00 0.40 -0.75 4.18 3.85 1afoA5 ILE 76 HB 0.01 0.03 0.13 -0.04 1.89 2.02 1afoA5 ILE 76 HG12 0.00 -0.00 -0.01 -0.04 1.49 1.44 1afoA5 ILE 76 HG13 -0.01 0.21 -0.15 -0.04 1.21 1.22 1afoA5 ILE 76 HG23 0.02 -0.01 -0.01 -0.04 0.93 0.89 1afoA5 ILE 76 HD13 -0.00 -0.02 -0.09 -0.04 0.88 0.72 1afoA5 ILE 77 H 0.02 0.77 -0.08 -0.55 8.25 8.42 1afoA5 ILE 77 HA 0.08 -0.02 0.41 -0.75 4.18 3.89 1afoA5 ILE 77 HB 0.13 0.12 0.17 -0.04 1.89 2.28 1afoA5 ILE 77 HG12 0.02 0.13 0.11 -0.04 1.49 1.71 1afoA5 ILE 77 HG13 0.04 -0.05 -0.02 -0.04 1.21 1.14 1afoA5 ILE 77 HG23 0.16 -0.02 -0.02 -0.04 0.93 1.00 1afoA5 ILE 77 HD13 0.04 -0.01 0.02 -0.04 0.88 0.89 1afoA5 PHE 78 H 0.27 0.58 -0.15 -0.55 8.34 8.49 1afoA5 PHE 78 HA 0.00 -0.03 0.42 -0.75 4.62 4.26 1afoA5 PHE 78 HB2 0.00 0.10 0.30 -0.04 3.15 3.52 1afoA5 PHE 78 HB3 0.00 -0.06 0.02 -0.04 3.06 2.98 1afoA5 PHE 78 HD2 0.00 -0.08 -0.00 -0.04 7.28 7.16 1afoA5 PHE 78 HE2 0.00 -0.02 0.00 -0.04 7.38 7.32 1afoA5 PHE 78 HZ 0.00 -0.01 0.00 -0.04 7.32 7.27 1afoA5 GLY 79 H 0.15 0.84 -0.04 -0.55 8.43 8.84 1afoA5 GLY 79 HA2 0.07 -0.03 0.42 -0.51 4.01 3.96 1afoA5 GLY 79 HA3 0.06 0.04 0.35 -0.51 4.01 3.95 1afoA5 VAL 80 H 0.07 0.59 -0.11 -0.55 8.24 8.24 1afoA5 VAL 80 HA 0.03 -0.02 0.42 -0.75 4.13 3.80 1afoA5 VAL 80 HB 0.05 0.15 0.21 -0.04 2.12 2.48 1afoA5 VAL 80 HG13 0.02 -0.03 -0.04 -0.04 0.97 0.88 1afoA5 VAL 80 HG23 0.03 -0.02 0.06 -0.04 0.95 0.98 1afoA5 MET 81 H 0.05 0.61 -0.10 -0.55 8.47 8.49 1afoA5 MET 81 HA -0.01 -0.03 0.42 -0.75 4.52 4.14 1afoA5 MET 81 HB2 -0.08 0.12 0.20 -0.04 2.15 2.35 1afoA5 MET 81 HB3 -0.07 -0.07 0.07 -0.04 2.03 1.92 1afoA5 MET 81 HG2 0.03 -0.07 0.10 -0.04 2.63 2.65 1afoA5 MET 81 HG3 0.05 0.06 -0.07 -0.04 2.56 2.57 1afoA5 MET 81 HE3 0.02 -0.01 -0.00 -0.04 2.10 2.07 1afoA5 ALA 82 H 0.01 0.82 -0.05 -0.55 8.40 8.63 1afoA5 ALA 82 HA -0.02 -0.05 0.42 -0.75 4.34 3.94 1afoA5 ALA 82 HB3 0.01 0.01 0.11 -0.04 1.41 1.51 1afoA5 GLY 83 H 0.01 0.70 -0.09 -0.55 8.43 8.50 1afoA5 GLY 83 HA2 0.01 -0.04 0.42 -0.51 4.01 3.89 1afoA5 GLY 83 HA3 0.01 0.05 0.36 -0.51 4.01 3.92 1afoA5 VAL 84 H 0.00 0.57 -0.11 -0.55 8.24 8.15 1afoA5 VAL 84 HA 0.00 -0.03 0.42 -0.75 4.13 3.77 1afoA5 VAL 84 HB -0.01 0.18 0.24 -0.04 2.12 2.49 1afoA5 VAL 84 HG13 -0.00 -0.03 -0.05 -0.04 0.97 0.85 1afoA5 VAL 84 HG23 0.00 -0.02 0.06 -0.04 0.95 0.95 1afoA5 ILE 85 H -0.01 0.63 -0.08 -0.55 8.25 8.23 1afoA5 ILE 85 HA -0.01 -0.04 0.42 -0.75 4.18 3.79 1afoA5 ILE 85 HB -0.02 0.15 0.22 -0.04 1.89 2.20 1afoA5 ILE 85 HG12 -0.03 -0.06 0.05 -0.04 1.49 1.41 1afoA5 ILE 85 HG13 -0.03 0.28 0.07 -0.04 1.21 1.48 1afoA5 ILE 85 HG23 -0.02 -0.04 -0.04 -0.04 0.93 0.79 1afoA5 ILE 85 HD13 -0.06 -0.02 -0.02 -0.04 0.88 0.74 1afoA5 GLY 86 H -0.00 0.75 -0.06 -0.55 8.43 8.58 1afoA5 GLY 86 HA2 0.01 -0.04 0.41 -0.51 4.01 3.88 1afoA5 GLY 86 HA3 0.01 0.05 0.35 -0.51 4.01 3.91 1afoA5 THR 87 H 0.01 0.64 -0.09 -0.55 8.28 8.29 1afoA5 THR 87 HA 0.01 -0.03 0.42 -0.75 4.39 4.04 1afoA5 THR 87 HB 0.01 0.18 0.23 -0.04 4.32 4.69 1afoA5 THR 87 HG23 0.01 -0.03 -0.03 -0.04 1.22 1.13 1afoA5 ILE 88 H 0.01 0.59 -0.11 -0.55 8.25 8.19 1afoA5 ILE 88 HA 0.01 -0.03 0.42 -0.75 4.18 3.82 1afoA5 ILE 88 HB -0.00 0.16 0.22 -0.04 1.89 2.23 1afoA5 ILE 88 HG12 0.00 -0.07 0.05 -0.04 1.49 1.44 1afoA5 ILE 88 HG13 0.00 0.26 0.13 -0.04 1.21 1.56 1afoA5 ILE 88 HG23 0.00 -0.04 -0.02 -0.04 0.93 0.84 1afoA5 ILE 88 HD13 -0.01 -0.03 -0.03 -0.04 0.88 0.77 1afoA5 LEU 89 H 0.01 0.74 -0.06 -0.55 8.37 8.51 1afoA5 LEU 89 HA 0.01 -0.04 0.42 -0.75 4.35 3.99 1afoA5 LEU 89 HB2 -0.00 -0.07 0.10 -0.04 1.64 1.63 1afoA5 LEU 89 HB3 0.00 0.14 0.18 -0.04 1.64 1.92 1afoA5 LEU 89 HG 0.04 0.14 0.11 -0.04 1.64 1.89 1afoA5 LEU 89 HD13 0.05 -0.04 -0.20 -0.04 0.93 0.69 1afoA5 LEU 89 HD23 0.01 -0.03 0.03 -0.04 0.89 0.86 1afoA5 LEU 90 H 0.04 0.69 -0.08 -0.55 8.37 8.47 1afoA5 LEU 90 HA 0.11 -0.03 0.42 -0.75 4.35 4.10 1afoA5 LEU 90 HB2 0.03 0.17 0.25 -0.04 1.64 2.05 1afoA5 LEU 90 HB3 0.03 -0.05 0.01 -0.04 1.64 1.59 1afoA5 LEU 90 HG 0.03 -0.03 0.03 -0.04 1.64 1.63 1afoA5 LEU 90 HD13 0.05 -0.02 0.04 -0.04 0.93 0.97 1afoA5 LEU 90 HD23 0.05 0.06 0.01 -0.04 0.89 0.98 1afoA5 ILE 91 H 0.03 0.60 -0.11 -0.55 8.25 8.22 1afoA5 ILE 91 HA 0.03 -0.03 0.42 -0.75 4.18 3.84 1afoA5 ILE 91 HB 0.02 0.15 0.21 -0.04 1.89 2.23 1afoA5 ILE 91 HG12 0.01 -0.07 0.06 -0.04 1.49 1.45 1afoA5 ILE 91 HG13 0.02 0.37 0.13 -0.04 1.21 1.69 1afoA5 ILE 91 HG23 0.01 -0.03 0.00 -0.04 0.93 0.87 1afoA5 ILE 91 HD13 0.01 -0.03 -0.01 -0.04 0.88 0.81 1afoA5 SER 92 H 0.04 0.64 -0.09 -0.55 8.46 8.50 1afoA5 SER 92 HA 0.03 -0.03 0.41 -0.75 4.49 4.15 1afoA5 SER 92 HB2 0.02 0.13 0.23 -0.04 3.95 4.29 1afoA5 SER 92 HB3 0.01 -0.02 0.02 -0.04 3.93 3.90 1afoA5 TYR 93 H 0.14 0.65 -0.09 -0.55 8.29 8.44 1afoA5 TYR 93 HA -0.00 -0.03 0.41 -0.75 4.56 4.18 1afoA5 TYR 93 HB2 -0.00 0.05 0.16 -0.04 3.06 3.23 1afoA5 TYR 93 HB3 -0.00 0.07 0.15 -0.04 2.98 3.16 1afoA5 TYR 93 HD2 -0.00 -0.02 0.11 -0.04 7.15 7.19 1afoA5 TYR 93 HE2 -0.00 -0.01 -0.00 -0.04 6.85 6.80 1afoA5 GLY 94 H 0.10 0.70 -0.05 -0.55 8.43 8.64 1afoA5 GLY 94 HA2 -0.04 -0.03 0.42 -0.51 4.01 3.85 1afoA5 GLY 94 HA3 0.01 0.01 0.35 -0.51 4.01 3.87 1afoA5 ILE 95 H 0.05 0.77 -0.05 -0.55 8.25 8.47 1afoA5 ILE 95 HA 0.02 -0.04 0.41 -0.75 4.18 3.82 1afoA5 ILE 95 HB 0.04 0.14 0.24 -0.04 1.89 2.26 1afoA5 ILE 95 HG12 0.01 -0.05 0.03 -0.04 1.49 1.44 1afoA5 ILE 95 HG13 0.02 -0.04 0.05 -0.04 1.21 1.19 1afoA5 ILE 95 HG23 0.02 -0.03 -0.09 -0.04 0.93 0.79 1afoA5 ILE 95 HD13 0.02 0.05 -0.14 -0.04 0.88 0.77 1afoA5 ARG 96 H 0.09 0.67 -0.08 -0.55 8.46 8.58 1afoA5 ARG 96 HA 0.04 -0.06 0.40 -0.75 4.34 3.98 1afoA5 ARG 96 HB2 0.06 -0.05 0.12 -0.04 1.90 1.99 1afoA5 ARG 96 HB3 0.20 0.14 0.22 -0.04 1.80 2.32 1afoA5 ARG 96 HG2 0.12 0.01 -0.13 -0.04 1.67 1.62 1afoA5 ARG 96 HG3 0.05 -0.03 -0.00 -0.04 1.67 1.65 1afoA5 ARG 96 HD2 0.01 -0.04 -0.03 -0.04 3.22 3.12 1afoA5 ARG 96 HD3 0.01 -0.03 0.00 -0.04 3.22 3.17 1afoA5 ARG 97 H 0.10 0.54 -0.08 -0.55 8.46 8.47 1afoA5 ARG 97 HA 0.04 0.19 0.54 -0.75 4.34 4.36 1afoA5 ARG 97 HB2 -0.04 0.03 0.19 -0.04 1.90 2.04 1afoA5 ARG 97 HB3 -0.03 -0.00 0.09 -0.04 1.80 1.82 1afoA5 ARG 97 HG2 -0.02 -0.01 0.05 -0.04 1.67 1.65 1afoA5 ARG 97 HG3 -0.02 -0.05 0.11 -0.04 1.67 1.67 1afoA5 ARG 97 HD2 -0.09 -0.01 0.01 -0.04 3.22 3.09 1afoA5 ARG 97 HD3 -0.09 -0.07 0.02 -0.04 3.22 3.04 1afoA5 LEU 98 H 0.02 0.53 -0.09 -0.55 8.37 8.28 1afoA5 LEU 98 HA 0.00 -0.04 0.36 -0.75 4.35 3.92 1afoA5 LEU 98 HB2 0.01 0.12 0.22 -0.04 1.64 1.95 1afoA5 LEU 98 HB3 0.01 -0.09 -0.00 -0.04 1.64 1.52 1afoA5 LEU 98 HG -0.00 0.01 0.06 -0.04 1.64 1.66 1afoA5 LEU 98 HD13 0.00 -0.04 -0.05 -0.04 0.93 0.80 1afoA5 LEU 98 HD23 -0.00 -0.02 0.02 -0.04 0.89 0.84 1afoA5 ILE 99 H 0.02 0.54 -0.09 -0.55 8.25 8.18 1afoA5 ILE 99 HA 0.01 -0.02 0.53 -0.75 4.18 3.94 1afoA5 ILE 99 HB 0.01 -0.11 0.08 -0.04 1.89 1.83 1afoA5 ILE 99 HG12 0.02 0.02 0.08 -0.04 1.49 1.57 1afoA5 ILE 99 HG13 0.02 0.36 0.16 -0.04 1.21 1.72 1afoA5 ILE 99 HG23 0.01 0.02 0.03 -0.04 0.93 0.95 1afoA5 ILE 99 HD13 0.01 -0.06 -0.04 -0.04 0.88 0.75 1afoA5 LYS 100 H 0.02 0.69 -0.12 -0.55 8.42 8.45 1afoA5 LYS 100 HA 0.01 0.03 0.78 -0.75 4.32 4.39 1afoA5 LYS 100 HB2 0.03 0.04 0.00 -0.04 1.87 1.90 1afoA5 LYS 100 HB3 0.02 -0.11 -0.04 -0.04 1.79 1.62 1afoA5 LYS 100 HG2 0.01 0.30 0.02 -0.04 1.46 1.75 1afoA5 LYS 100 HG3 0.01 -0.08 -0.12 -0.04 1.46 1.23 1afoA5 LYS 100 HD2 0.01 -0.05 -0.01 -0.04 1.69 1.60 1afoA5 LYS 100 HD3 0.01 -0.04 0.06 -0.04 1.68 1.67 1afoA5 LYS 100 HE2 0.01 0.05 0.01 -0.04 2.99 3.02 1afoA5 LYS 100 HE3 0.01 -0.05 0.00 -0.04 2.99 2.90 1afoA5 LYS 101 H 0.01 0.00 0.06 -0.55 8.42 7.94 1afoA5 LYS 101 HA 0.01 -0.04 0.22 -0.75 4.32 3.76 1afoA5 LYS 101 HB2 0.04 0.12 -0.55 -0.04 1.87 1.43 1afoA5 LYS 101 HB3 0.02 -0.01 0.19 -0.04 1.79 1.95 1afoA5 LYS 101 HG2 0.03 -0.02 -0.00 -0.04 1.46 1.43 1afoA5 LYS 101 HG3 0.02 -0.03 0.04 -0.04 1.46 1.45 1afoA5 LYS 101 HD2 0.02 -0.03 -0.05 -0.04 1.69 1.58 1afoA5 LYS 101 HD3 0.04 0.03 -0.13 -0.04 1.68 1.57 1afoA5 LYS 101 HE2 0.02 -0.01 -0.03 -0.04 2.99 2.93 1afoA5 LYS 101 HE3 0.03 -0.01 -0.02 -0.04 2.99 2.95